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[Ir(dtbbpy)(ppy)2][PF6]

[Ir(dtbbpy)(ppy)2][PF6] Structure
  • ₹8524.8 - ₹19600
  • Product name: [Ir(dtbbpy)(ppy)2][PF6]
  • CAS: 676525-77-2
  • MF: C40H40F6IrN4P
  • MW: 913.97
  • EINECS:
  • MDL Number:MFCD28369259
  • Synonyms:[Ir(dtbbpy)(ppy)2][PF6];(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate;(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate;[Ir(dtbbpy)(ppy);(4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%;[4,4'-Bis(tert-butyl)-2,2'-bipyridine]bis[2-(2-pyridinyl)phenyl]iridium(III) hexafluorophosphate;(4,4'-Di-tert-butyl-2,2'-bipyridine)di[(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate;-2,2'-bipyridine)bis[(2-pyridinyL
3 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 50MG
  • 100MG
  • 200MG
  • ManufacturerTCI Chemicals (India)
  • Product numberD4887
  • Product description(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
  • Packaging200MG
  • Price₹19600
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number747769
  • Product description[Ir(dtbbpy)(ppy)2]PF6
  • Packaging50MG
  • Price₹8524.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number747769
  • Product description[Ir(dtbbpy)(ppy)2]PF6
  • Packaging100MG
  • Price₹17737.8
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) D4887 (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate 200MG ₹19600 2022-05-26 Buy
Sigma-Aldrich(India) 747769 [Ir(dtbbpy)(ppy)2]PF6 50MG ₹8524.8 2022-06-14 Buy
Sigma-Aldrich(India) 747769 [Ir(dtbbpy)(ppy)2]PF6 100MG ₹17737.8 2022-06-14 Buy

Properties

storage temp. :2-8°C
form :crystal
color :yellow
λmax :380nm(CH2Cl2)(lit.)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Description

[Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:
  • Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
  • Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
  • Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
  • Aryl-alkyl C?C reductive cross-coupling reactions.


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